RTO care

PM Designation

관련규제2016. 6. 27. 08:13

This Web site provides information about EPA's actions designating areas whose air quality does not meet the health-based standards established in 1997, 2006, and 2012 for fine particle pollution.

The Clean Air Act requires EPA to issue designations after the agency sets a new National Ambient Air Quality Standard (NAAQS) or revises an existing standard. EPA formally designates areas as "nonattainment" (not meeting the standard), "unclassifiable/attainment" (meeting the standard or expected to be meeting the standard despite a lack of monitoring data), or "unclassifiable" (insufficient data to classify).

Once nonattainment designations take effect, the state and local governments must develop implementation plans outlining how areas will attain and maintain the standards by reducing air pollutant emissions contributing to fine particle concentrations.

EPA strengthened the air quality standards for particle pollution in 2006 and 2012. Learn more about the 2012 standards.

EPA will assist states and tribes throughout the initial area designations process for the 2012 annual PM2.5 NAAQS by providing technical and policy-related information relevant to making designations decisions. See Area Designations for the 2012 Annual PM2.5 Standard.

Area designations for the 2006 fine particle standard became effective in 2009 for most areas. Area designations became effective in March 2011 for deferred areas identified in the February 2011 Federal Register designations notice and in November 2012 for the two tribal areas identified in the October 2012 Federal Register designations notice. Learn more about the area designations for the 2006 daily fine particle standards.

Area designations for the 1997 fine particle standard became effective in 2005. Learn more about the area designations for the 1997 fine particle standards.

   

원본 위치 <http://www.epa.gov/pmdesignations/>

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PM standards

관련규제2016. 6. 27. 08:12

Particulate Matter (PM) Standards -

Table of Historical PM NAAQS

History of the National Ambient Air Quality Standards for Particulate Matter

During the Period 1971-2012

Final Rule

Primary/ Secondary

Indicator

Averaging

Time

Level (1)

Form

1971

   

36 FR 8186

Apr 30, 1971

Primary

TSP (2)

24-hour

260 µg/m3

Not to be exceeded more than once per year

  

  

  

Annual

75 µg/m3

Annual Average

  

Secondary

TSP

24-hour

150 µg/m3

Not to be exceeded more than once per year

1987

   

52 FR 24634

Jul 1, 1987

Primary and Secondary

PM10

24-hour

150 µg/m3

Not to be exceeded more than once per year on average over a 3-year period

  

  

  

Annual

50 µg/m3

Annual arithmetic mean, averaged over 3 years

1997

   

62 FR 38652

Jul 18, 1997

Primary and Secondary

PM2.5

24-hour

65 µg/m3

98th percentile, averaged over 3 years

  

  

  

Annual

15.0 µg/m3

Annual arithmetic mean, averaged over 3 years (3),(4)

  

  

PM10

24-hour

150 µg/m3

Initially promulgated 99th percentile, averaged over 3 years; when 1997 standards for PM10 were vacated, the form of 1987 standards remained in place (not to be exceeded more than once per year on average over a 3-year period) (5)

  

  

  

Annual

50 µg/m3

Annual arithmetic mean, averaged over 3 years

2006

   

71 FR 61144

Oct 17, 2006

Primary and Secondary

PM2.5

24-hour

35 µg/m3

98th percentile, averaged over 3 years (6)

  

  

  

Annual

15.0 µg/m3

Annual arithmetic mean, averaged over 3 years (2), (7)

  

  

PM10

24-hour (8)

150 µg/m3

Not to be exceeded more than once per year on average over a 3-year period

2012

Primary

PM2.5

Annual

12.0 µg/m3

Annual arithmetic mean, averaged over 3 years (2), (7)

  

Secondary

  

Annual

15.0 µg/m3

Annual arithmetic mean, averaged over 3 years (2), (7)

  

Primary and Secondary

  

24-hour

35 µg/m3

98th percentile, averaged over 3 years (6)

  

Primary and Secondary

PM10

24-hour (8)

150 µg/m3

Not to be exceeded more than once per year on average over a 3-year period

(1) Units of measure are micrograms per cubic meter of air (µg/m3).

(2) TSP = total suspended particles.

(3)The level of the annual standard is defined to one decimal place (i.e., 15.0 µg/m3) as determined by rounding.  For example, a 3-year average annual mean of 15.04 µg/m3 would round to 15.0 µg/m3 and, thus, meet the annual standard and a 3-year average of 15.05 µg/m3 would round to 15.1 µg/m3 and, hence, violate the annual standard (40 CFR part 50 Appendix N).

(4)The level of the standard was to be compared to measurements made at sites that represent "community-wide air quality" recording the highest level, or, if specific requirements were satisfied, to average measurements from multiple community-wide air quality monitoring sites ("spatial averaging").

(5) See 69 FR 45592, July 30, 2004.

(6) The level of the 24-hour standard is defined as an integer (zero decimal places) as determined by rounding.  For example, a 3-year average 98th percentile concentration of 35.49 µg/m3 would round to 35 µg/m3 and thus meet the 24-hour standard and a 3-year average of 35.50 µg/m3 would round to 36 and, hence, violate the 24-hour standard (40 CFR part 50 Appendix N).

(7) The EPA tightened the constraints on the spatial averaging criteria by further limiting the conditions under which some areas may average measurements from multiple community-oriented monitors to determine compliance (see 71 FR 61165-61167).

(8) The EPA revoked the annual PM10 NAAQS in 2006.

   

원본 위치 <http://www.epa.gov/ttn/naaqs/standards/pm/s_pm_history.html>

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PM standard

관련규제2016. 6. 27. 03:24

National Ambient Air Quality Standards (NAAQS)

The Clean Air Act, which was last amended in 1990, requires EPA to set National Ambient Air Quality Standards (40 CFR part 50) for pollutants considered harmful to public health and the environment. The Clean Air Act identifies two types of national ambient air quality standards. Primary standards provide public health protection, including protecting the health of "sensitive" populations such as asthmatics, children, and the elderly. Secondary standards provide public welfare protection, including protection against decreased visibility and damage to animals, crops, vegetation, and buildings.

EPA has set National Ambient Air Quality Standards for six principal pollutants, which are called "criteria" pollutants. They are listed below. Units of measure for the standards are parts per million (ppm) by volume, parts per billion (ppb) by volume, and micrograms per cubic meter of air (µg/m3).

 

Pollutant

[final rule cite]

  

Primary/

Secondary

Averaging Time

Level

Form

Carbon Monoxide

[76 FR 54294, Aug 31, 2011]

  

primary

8-hour

9 ppm

Not to be exceeded more than once per year

  

  

  

1-hour

35 ppm

  

Lead

[73 FR 66964, Nov 12, 2008]

  

primary and

secondary

Rolling 3 month average

0.15 μg/m3 (1)

Not to be exceeded

Nitrogen Dioxide

[75 FR 6474, Feb 9, 2010]

[61 FR 52852, Oct 8, 1996]

  

primary

1-hour

100 ppb

98th percentile, averaged over 3 years

  

  

primary and

secondary

Annual

53 ppb (2)

Annual Mean

Ozone

[73 FR 16436, Mar 27, 2008]

  

primary and

secondary

8-hour

0.075 ppm (3)

Annual fourth-highest daily maximum 8-hr concentration, averaged over 3 years

Particle Pollution

Dec 14, 2012

PM2.5

primary

Annual

12 μg/m3

annual mean, averaged over 3 years

  

  

secondary

Annual

15 μg/m3

annual mean, averaged over 3 years

  

  

primary and

secondary

24-hour

35 μg/m3

98th percentile, averaged over 3 years

  

PM10

primary and

secondary

24-hour

150 μg/m3

Not to be exceeded more than once per year on average over 3 years

Sulfur Dioxide

[75 FR 35520, Jun 22, 2010]

[38 FR 25678, Sept 14, 1973]

  

primary

1-hour

75 ppb (4)

99th percentile of 1-hour daily maximum concentrations, averaged over 3 years

  

  

secondary

3-hour

0.5 ppm

Not to be exceeded more than once per year

as of October 2011

(1) Final rule signed October 15, 2008.  The 1978 lead standard (1.5 µg/m3 as a quarterly average) remains in effect until one year after an area is designated for the 2008 standard, except that in areas designated nonattainment for the 1978, the 1978 standard remains in effect until implementation plans to attain or maintain the 2008 standard are approved.

(2) The official level of the annual NO2 standard is 0.053 ppm, equal to 53 ppb, which is shown here for the purpose of clearer comparison to the 1-hour standard.

(3) Final rule signed March 12, 2008.  The 1997 ozone standard (0.08 ppm, annual fourth-highest daily maximum 8-hour concentration, averaged over 3 years) and related implementation rules remain in place.  In 1997, EPA revoked the 1-hour ozone standard (0.12 ppm, not to be exceeded more than once per year) in all areas, although some areas have continued obligations under that standard ("anti-backsliding").  The 1-hour ozone standard is attained when the expected number of days per calendar year with maximum hourly average concentrations above 0.12 ppm is less than or equal to 1.

(4) Final rule signed June 2, 2010.  The 1971 annual and 24-hour SO2 standards were revoked in that same rulemaking.  However, these standards remain in effect until one year after an area is designated for the 2010 standard, except in areas designated nonattainment for the 1971 standards, where the 1971 standards remain in effect until implementation plans to attain or maintain the 2010 standard are approved.

See historical tables of NAAQS standards

Menu of Control Measures for NAAQS Implementation

The Menu of Control Measures (MCM) provides state, local and tribal air agencies with the existing emission reduction measures as well as relevant information concerning the efficiency and cost effectiveness of the measures.  State, local and tribal agencies will be able to use this information in developing emission reduction strategies, plans and programs to assure they attain and maintain the National Ambient Air Quality Standards (NAAQS).  The MCM is a living document that can be updated with newly available or more current data as it becomes available.

   

원본 위치 <http://www.epa.gov/air/criteria.html>

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Health

The size of particles is directly linked to their potential for causing health problems. Small particles less than10 micrometers in diameter pose the greatest problems, because they can get deep into your lungs, and some may even get into your bloodstream.

Exposure to such particles can affect both your lungs and your heart. Small particles of concern include "inhalable coarse particles" (such as those found near roadways and dusty industries), which are larger than 2.5 micrometers and smaller than 10 micrometers in diameter; and "fine particles" (such as those found in smoke and haze), which are 2.5 micrometers in diameter and smaller.

The Clean Air Act requires EPA to set air quality standards to protect both public health and the public welfare (e.g. visibility, crops and vegetation). Particle pollution affects both.

Health Effects

Particle pollution - especially fine particles - contains microscopic solids or liquid droplets that are so small that they can get deep into the lungs and cause serious health problems. Numerous scientific studies have linked particle pollution exposure to a variety of problems, including:

  • premature death in people with heart or lung disease,
  • nonfatal heart attacks,
  • irregular heartbeat,
  • aggravated asthma,
  • decreased lung function, and
  • increased respiratory symptoms, such as irritation of the airways, coughing or difficulty breathing.

    People with heart or lung diseases, children and older adults are the most likely to be affected by particle pollution exposure. However, even if you are healthy, you may experience temporary symptoms from exposure to elevated levels of particle pollution. For more information about asthma, visit www.epa.gov/asthma.

    Environmental Effects

    Visibility impairment

    Fine particles (PM2.5) are the main cause of reduced visibility (haze) in parts of the United States, including many of our treasured national parks and wilderness areas. For more information about visibility, visit www.epa.gov/visibility.

    Environmental damage

    Particles can be carried over long distances by wind and then settle on ground or water.  The effects of this settling include: making lakes and streams acidic; changing the nutrient balance in coastal waters and large river basins; depleting the nutrients in soil; damaging sensitive forests and farm crops; and affecting the diversity of ecosystems. More information about the effects of particle pollution and acid rain.

    Aesthetic damage

    Particle pollution can stain and damage stone and other materials, including culturally important objects such as statues and monuments. More information about the effects of particle pollution and acid rain.

    You will need Adobe Acrobat Reader to view the Adobe PDF files on this page. See EPA's PDF page for more information about getting and using the free Acrobat Reader.

    For more information on particle pollution, health and the environment, visit:

    Particle Pollution and Your Health (PDF) (2pp, 320k): Learn who is at risk from exposure to particle pollution, what health effects you may experience as a result of particle exposure, and simple measures you can take to reduce your risk.

    How Smoke From Fires Can Affect Your Health: It's important to limit your exposure to smoke -- especially if you may be susceptible. This publication provides steps you can take to protect your health.

    Integrated Science Assessment for Particulate Matter (December 2009): This comprehensive assessment of scientific data about the health and environmental effects of particulate matter is an important part of EPA's review of its particle pollution standards.

       

    원본 위치 <http://www.epa.gov/air/particlepollution/health.html>

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Basic Information

Particle pollution (also called particulate matter or PM) is the term for a mixture of solid particles and liquid droplets found in the air. Some particles, such as dust, dirt, soot, or smoke, are large or dark enough to be seen with the naked eye. Others are so small they can only be detected using an electron microscope.

How Big is Particle Pollution?

See a larger version of the image here

Particle pollution includes "inhalable coarse particles," with diameters larger than 2.5 micrometers and smaller than 10 micrometers and "fine particles," with diameters that are 2.5 micrometers and smaller. How small is 2.5 micrometers? Think about a single hair from your head. The average human hair is about 70 micrometers in diameter – making it 30 times larger than the largest fine particle.

These particles come in many sizes and shapes and can be made up of hundreds of different chemicals. Some particles, known as primary particles are emitted directly from a source, such as construction sites, unpaved roads, fields, smokestacks or fires. Others form in complicated reactions in the atmosphere of chemicals such as sulfur dioxides and nitrogen oxides that are emitted from power plants, industries and automobiles. These particles, known as secondary particles, make up most of the fine particle pollution in the country.

EPA regulates inhalable particles (fine and coarse). Particles larger than 10 micrometers (sand and large dust) are not regulated by EPA. More about EPA PM Standards and Regulatory Actions.

  • Health: Particle pollution contains microscopic solids or liquid droplets that are so small that they can get deep into the lungs and cause serious health problems. The size of particles is directly linked to their potential for causing health problems. Small particles less than 10 micrometers in diameter pose the greatest problems, because they can get deep into your lungs, and some may even get into your bloodstream. More information about health.
  • Visibility: Fine particles (PM2.5) are the main cause of reduced visibility (haze) in parts of the United States, including many of our treasured national parks and wilderness areas. More information about visibility.
  • Reducing particle pollution: EPA's national and regional rules to reduce emissions of pollutants that form particle pollution will help state and local governments meet the Agency's national air quality standards. More information about reducing particle pollution.

    See the Fast Facts page for a quick summary of particle pollution basics.

       

    원본 위치 <http://www.epa.gov/air/particlepollution/basic.html>

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"Particulate matter," also known as particle pollution or PM, is a complex mixture of extremely small particles and liquid droplets. Particle pollution is made up of a number of components, including acids (such as nitrates and sulfates), organic chemicals, metals, and soil or dust particles.

The size of particles is directly linked to their potential for causing health problems. EPA is concerned about particles that are 10 micrometers in diameter or smaller because those are the particles that generally pass through the throat and nose and enter the lungs. Once inhaled, these particles can affect the heart and lungs and cause serious health effects. EPA groups particle pollution into two categories:

  • "Inhalable coarse particles," such as those found near roadways and dusty industries, are larger than 2.5 micrometers and smaller than 10 micrometers in diameter.
  • "Fine particles," such as those found in smoke and haze, are 2.5 micrometers in diameter and smaller. These particles can be directly emitted from sources such as forest fires, or they can form when gases emitted from power plants, industries and automobiles react in the air.

    Basic Information - Basics about particle pollution.

    Health - Effects of particle pollution.

    PM Standards - Links to technical information related to setting the national air quality standards for particle pollution.

    PM Designations - Regional, state and local information related to PM nonattainment.

    PM Implementation - Programs and requirements for reducing particle pollution.

    Regulatory Actions - Links to proposed and final rules, fact sheets, and other rulemaking documents.

    Nonattainment Areas - Status of nonattainment areas (the Green Book)

    PM Research - Links to PM research and development, monitoring, and daily reporting and forecasting.

    Agriculture - Fact Sheet - Coarse PM (PM10) standards and agriculture.

    Air Quality Trends - Progress made in reducing particle pollution.

    Air Emission Sources - Summarizes particulate matter emissions by source at national, state and local levels.

    Residential Wood Smoke - Burn Wise is a partnership program that emphasizes the importance of burning the right wood, the right way, in the right wood-burning appliance to protect your home, health, and the air we breathe.

    Related Links - Other information related to particle pollution.

    State Implementation Plan Status and Information - identifies how states and EPA work together to ensure that the agency's National Ambient Air Quality Standards (NAAQS) are met and maintained.

       

    원본 위치 <http://www.epa.gov/air/particlepollution/>

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증기압이 높아 대기중으로 쉽게 증발되어 질소산화물(Nox)과 공존시 태양광의 작용에 의하여 광화

학반응을 일으켜 오존 및 PAN(Peroxyacyl Nitrate)등 2차오염물질을 생성시킴으로써 광화학 스모

그 현상을 일으키는 물질을 휘발성유기화합물질(Volatile Organic Compounds, VOCs)이라고 한다.

가. 미국의 정의

대기중에서 광화학반응에 참여하는 물질중 일산화탄소, 이산화탄소, 탄산, 금속성 탄화물, 탄산염,

탄산암모늄을 제외한 모든 탄소화합물이라고 EPA는 CAA(Clean Air Act)의 TitleⅠ에 따른 정부의

실행계획을 준비, 채택, 시행하기 위한 언급에서 정의하고 있다. 광화학반응에 대한 영향이 무시될

정도인 유기화합물에 대해서는 법규제로부터 제외시키고 표준상태(20℃, 760mmHg)에서 증기압

이 0.1mmHg이상이 되는 유기화합물을 VOCs로 간주한다.

나. 일본의 정의

유기화합물중 원유, 가솔린, 나프타 및 항공터빈연료유 4호, 기타 단일물질은 1기압에서 비점이

150℃이하인 물질, 혼합물질은 1기압에서 전체5%의 유출점이 150℃이하인 물질을 VOCs이라 규정

하고 있으며 이중 일산화탄소, 탄산 및 그염류, 메탄, 에탄, 클로로에탄 및 트리할로트리플로로 에

탄등 광화학 반응성이 낮은 화합물은 제외시키고 있다.

다. 국내법상의 정의

"탄화수소류중 레이드 증기압이 10.3 킬로파스칼 (또는 1.5 psia)이상인 석유화학제품·유기용제 기

타 물질로서 환경부장관이 관계 중앙행정기관의 장과 협의하여 고시하는 물질 (대기환경보전법시

행령 제39조 제1항)로 정의하고 있으며 환경부고시 제2001-36호(2001.3.8)에 따라 벤젠, 부타디엔,

휘발유등 37개 물질 및 제품을 규제대상으로 하고 있다."

   

원본 위치 <http://www.devocs.co.kr/n/vocs_intro.htm>

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1) 물질자체가 직접적으로 인체에 유해(방향족 또는 할로겐족 탄화수소)

방향족 탄화수소 : 벤젠, 톨루엔, 자일렌등

할로겐 탄화수소 : Cl, F를 포함한 탄화수소

2) 인체에 대한 유해성은 크지 않으나 광화학반응을 통하여 스모그 발생의 원인이 됨

(지방족 탄화수소류, 특히 올레핀계)

3) 지표면 부근에서 오존의 생성에 관여하여 결과적으로 지구온난화에 간접적으로 기여

4) 성층권 오존층 파괴원인 물질(프레온)

5) 반응성이 약하여 장기간 대기중에 체류하여 환경에 누적되거나 축적되어

인간을 포함한 자연생태계에 영향을 미침(PCB)

VOCs의 유해성

오존 생성

1. 휘발성유기화합물질의 유해성

"고농도 VOC에 노출시 마취작용(중추신경계 억제), 현기증, 마비 및 사망등 급성장애를 일으

키며, 물질별 특이독성은 아래와 같음."

물질

건강장해

벤젠

조혈기능 장해(혈구감소증, 재생불량성 빈혈),부정맥, 발암성(백혈병)

할로겐화

탄화수소 간독성, 신독성, 심장독성(부정맥, 돌연사), 동물에서 발암성

메탄올

시력상실, 대사성 산증

포름알데히드

알레르기성 피부염, 폐기능 저하, 동물에서의 발암성

노르말 헥산

말초신경 장해

2. 오존 생성

VOC의 대기중 광화학반응

"대기중의 휘발성유기화합물질(VOC)의 가장 중요한 역할은 NOx와 같이 존재하여 OH

Radical과 반응, 오존을 생성시켜서 광화학옥시단트의 원인물질이 됨."

VOC + 2NO + 2O2 → H2O + 2NO2 + R′C(O) R′

NO2 + hv → NO + O

O + O2 + M → O3 + M

   

∴ VOC + 3O2 → H2O + O3 + R′C(O) R′

- NOx와 같이 존재하는 VOC가 오존의 생성원인이 됨

- 오존 농도별 사망자 실태

"1991년에서 1996년까지 서울시를 대상으로 오존오염과 사망자수의 관계를 분석한 결과 오존농

도가 0.1ppm증가하면 평소보다 3-10%정도의 사망자가 추가발생."

   

원본 위치 <http://www.devocs.co.kr/n/vocs_spec.htm>

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흡착시설

관련기술2016. 6. 27. 03:06

원리 :

활성탄 및 실리카겔 등 흡착제에 의한 악취 성분의 흡착제거

장점 :

- 저농도 취기에 효과적이다.

  

- 탈취효율이 높다.

  

- 장치구조가 간단하다.

  

- 폐수발생이 없다.

단점 :

- 타르, 분진 및 점착성 물질을 포함한 악취의 경우 제거를 위한 전처리가 필요하다.

  

- 화재위험이 있다.

  

- 주기적인 활성탄 재생 및 교환이 필요하다.

  

- 2차폐기물이 발생된다.

  

- 유지관리비가 비싸다.

  

- 처리대상 물질에 따라 적용의 제한이 크다.

악취물질 :

- 흡착제에 따라 처리효율에 차이가 있다.

  

- 흡착제의 조합에 따라 발생악취의 전물질에 대하여 효과적이다.

(점착활성탄+중성활성탄)

장치의 특성 :

- 가스의 중성, 산성, 알카리성에 따라 활성탄 사용이 결정된다.

  

- 암모니아 등 자극성이 강한 가스등의 흡착 제거가 어렵다.

탈취 효율 :

80% 이상

경제성 :

초기 시설투자비는 낮으나 운전비용은 높다.

   

원본 위치 <http://www.devocs.co.kr/n/vocs_tec1.htm>

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세정시설

관련기술2016. 6. 27. 03:05

원리 :

악취물질을 약액(산알카리)에 흡수시켜 화학적으로 중화하여 처리

장점 :

- Mist, 분진등의 동시 처리가 가능하다.

  

- 발생 VOCs 및 악취의 온도에 대한 적용이 용이하다.

  

- 고농도 취기에 효과적이다.

단점 :

- 발생폐수의 처리설비가 필요하다.

  

- 복합취기의 제거에 부적합하다.

  

- 약품취급에 주의를 요한다.

  

- 숙련된 운전기술이 필요하다.

  

- 시설비, 약품비가 높다.

  

- 약품저장 및 공급시설 등 부대시설이 필요하다.

악취물질 :

- 산세정 : 암모니아,아민류

  

- 알카리 세정 : 유화수소, 메르캅탄, 고급 지방산 등.

장치의 특성 :

- 가스의 수용액과의 친화성 및 기액접촉 효율에 따라 처리 효율이 결정된다.

탈취 효율 :

80% 이상

경제성 :

초기 시설투자비 및 운전비용 모두 높다.

   

원본 위치 <http://www.devocs.co.kr/n/vocs_tec2.htm>

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